Bis(3-azaniumylpyridin-1-ium) hexachloridostannate(IV) dichloride
نویسندگان
چکیده
The asymmetric unit of the title compound, (C5H8N2)2[SnCl6]Cl2, consists of one 3-aza-niumylpyridin-1-ium dication and one chloride ion in a general position and a hexa-chloridostannate(IV) dianion lying about a centre of inversion. The [SnCl6](2-) anion exhibits almost perfect octa-hedral geometry. The 3-aza-niumylpyridin-1-ium and chloride ions are connected via medium-strong charge-supported N-H⋯Cl hydrogen bonds, forming undulating layers in the (110) plane. The [SnCl6](2-) ions are located between these layers and occupy cavities formed by two facing layer puckers.
منابع مشابه
Bis(benzyltriethylammonium) hexachloridostannate(IV)
The reaction between benzyl-triethyl-ammonium chloride and dimethyl-tin dichloride yields the title salt, [(C(6)H(5)CH(2))(C(2)H(5))(3)N](2)[SnCl(6)]. The Sn(IV) atom, located on a center of inversion, exists in an octa-hedral coordination environment. The cation links with the anion via weak C-H⋯Cl hydrogen bonding.
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